The ability to model self-assembly at these larger length and time scales is a key requirement in gaining a molecular understanding in to a range of phenomenon in science and technology. The model we propose to develop and widely distribute with EPSRC funding will help keep the UK at the leading edge of nano-science and engineering applications. The tools we develop will be of interest to companies in the areas of technology and high-tech manufacturing. To exploit the tools we develop for commercial purposes we are in contact with the UK Company 'Oxford Nanopore Technologies', which is developing such nanopore gene sequencing technology see Letter of Support.
We will visit their company headquarters located in Oxford during the last half of this research programme, during which time Dr O'Brien will present his research to the company to discuss potential applications. Dr O'Brien will also get project management experience, which will help develop his professional skills. As new graduate students enter the research group he will have the opportunity to advise and mentor them in their research projects. We have a track record in the area of coarse-grained modelling that shows that our results have wide visibility through publication in high profile journals as well as presentation at international meetings.
Furthermore, our previous work has demonstrated successful collaborations with experimentalists, which will continue in our collaboration with Dr John Christodoulou as proposed in the application. Publications The following are buttons which change the sort order, pressing the active button will toggle the sort order Author Name descending press to sort ascending. Ciryam P In vivo translation rates can substantially delay the cotranslational folding of the Escherichia coli cytosolic proteome. O'Brien EP Trigger factor slows co-translational folding through kinetic trapping while sterically protecting the nascent chain from aberrant cytosolic interactions.
PS-SO 3 H meso silicas DSNs with enhanced acid strength and unique double-shell mesostructure show excellent catalytic activity and selectivity in a series of important acid-catalysed reactions. Our findings may offer a new approach to fabricate highly efficient solid acid catalysts for green chemical processes.
All materials were of analytical grade. Styrene was washed through an inhibitor remover column for removing the inhibitor and then distilled under vacuum before use. The other materials were used as received without any further purification. Other reagents were purchased from Shanghai Chemical Reagent, Inc. The PS template spheres were prepared by emulsion polymerization in a water system according to a modified method Specifically, PVP 0.
Then, 0. After polymerization reaction, the solution was centrifuged and washed with water and ethanol for three times. For characterization procedures, see Supplementary Methods. Then, TEOS 0. The mixture was stirred for 0. The second step involves selective etching according to the following procedure: BTME 0.
After centrifugation and washing with ethanol, the desired material was obtained.
Solid acids with DSN were obtained in one-pot step. The suspension was washed with copious amount of water until the filtrate was neutral. Esterification of lauric acid with ethanol was carried out in a two-necked round flask equipped with a reflux condenser and a magnetic stirrer. Tetradecane was used as an internal standard. Liquid-phase Friedel—Crafts alkylation of toluene by benzyl alcohol was carried out in a two-necked round-bottom flask coupled with a reflux condenser in a temperature-controlled oil bath.
In a typical experiment, 0. The CHP cleavage reaction was carried out in a round-bottom flask coupled with a reflux condenser in a temperature-controlled water bath. How to cite this article: Zhang, X.
Tag: macromolecular chemistry
Polystyrene sulphonic acid resins with enhanced acid strength via macromolecular self-assembly within confined nanospace. Corma, A. Inorganic solid acids and their use in acid-catalyzed hydrocarbon reactions. Solid acid catalysts. Solid State Mater. Lewis acids: from conventional homogeneous to green homogeneous and heterogeneous catalysis. Clark, J. Solid acids for green chemistry. Climent, M.
Parameters that Affect Macromolecular Self-Assembly of Prion Protein | SpringerLink
Heterogeneous catalysts for the one-pot synthesis of chemicals and fine chemicals. Pourjavadi, A. Multi-layer functionalized poly ionic liquid coated magnetic nanoparticles: highly recoverable and magnetically separable bronsted acid catalyst. ACS Catal.
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Liu, F. Transesterification catalyzed by ionic liquids on superhydrophobic mesoporous polymers: heterogeneous catalysts that are faster than homogeneous catalysts. Design and synthesis of mesoporous polymer-based solid acid catalysts with excellent hydrophobicity and extraordinary catalytic activity. Efficient and stable solid acid catalysts synthesized from sulfonation of swelling mesoporous polydivinylbenzenes. Siril, P. New polystyrene sulfonic acid resin catalysts with enhanced acidic and catalytic properties.
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Solid acid catalysis using ion-exchange resins. Hart, M. Sulfonated poly styrene-co-divinyl -benzene ion-exchange resins: acidities and catalytic activities in aqueous reactions. Barbaro, P. Ion exchange resins: catalyst recovery and recycle. Choi, M.
Controlled polymerization in mesoporous silica toward the design of organic-inorganic composite nanoporous materials. Acid hybrid catalysts from poly styrenesulfonic acid grafted onto ultra-large-pore SBA silica using atom transfer radical polymerization. Long, W. Hybrid sulfonic acid catalysts based on silica-supported poly styrene sulfonic acid brush materials and their application in ester hydrolysis. Li, C. Microporous Mesoporous Mater. Melero, J. Direct syntheses of ordered SBA mesoporous materials containing arenesulfonic acid groups. Siegel, R.
Understanding the high catalytic activity of propylsulfonic acid-functionalized periodic mesoporous benzenesilicas by high-resolution 1 H solid-state NMR spectroscopy. Mbaraka, I. Acid strength variation due to spatial location of organosulfonic acid groups on mesoporous silica. Brandle, M. Acidity differences between inorganic solids induced by their framework structure- a combined quantum mechanics molecular mechanics ab initio study on zeolites.
Dacquin, J. Interdependent lateral interactions, hydrophobicity and acid strength and their influence on the catalytic activity of nanoporous sulfonic acid silicas.
Green Chem. High-temperature synthesis of magnetically active and SO3H-functionalized ordered mesoporous carbon with good catalytic performance. Today , — Kitano, M. Selvaraj, M. Synthesis and characterization of mesoporous solid acid catalysts. Microporous and Mesoporous Mater. Kalita, P. Sijbesma, R. Reversible polymers formed from self-complementary monomers using quadruple H-bond.
Tag: macromolecular chemistry
Science , — Molecular Networks. Mir Wais Hosseini. Polycyclic Arenes and Heteroarenes. Qian Miao. Bridging Heterogeneous and Homogeneous Catalysis. Can Li. Intelligent Stimuli-Responsive Materials. Quan Li.
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